Bis(1-benzyl-3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7] decane) peroxodisulfate: A mild and efficient oxidation of organic compounds under anhydrous and aprotic conditions

Article abstract of DOI:10.1080/00397910008086921

Bis (1-benzyl-3,5,7-triaza-1-azoniatricyclo [3.3.1.1^3,7] decane) peroxodisulfate was readily prepared as an white solid from commercially available hexamethylenetetramine and potassium peroxodisulfate. This reagent could be used as a stable, mild and efficient oxidizer to produce the corresponding carbonyl compounds from hydroxyl compounds or hydrazones or oximes and disulfides from thiols under anhydrous and aprotic conditions. The yields were almost quantitative, and the reaction time was very short.

Full text of DOI:10.1080/00397910008086921

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Synthetic Communications: An
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Bis(1-Benzyl-3,5,7-Triaza-1-
3,7
Azoniatricyclo[3.3.1.1 ]
Decane) Peroxodisulfate: A
Mild and Efficient Oxidation
of Organic Compounds Under
Anhydrous and Aprotic
Conditions
a
b
b
Wu Minghu , Yang Guichun & Chen Zuxing
a
Department of Chemistry , Xianning Normal
College , Xianning, 437005, China
b
Faculty of Chemistry and Material Science, Hubei
University , Wuhan, 430062, China
Published online: 04 Dec 2007.
To cite this article: Wu Minghu , Yang Guichun & Chen Zuxing (2000) Bis(1-
3,7
Benzyl-3,5,7-Triaza-1-Azoniatricyclo[3.3.1.1 ] Decane) Peroxodisulfate: A Mild and
Efficient Oxidation of Organic Compounds Under Anhydrous and Aprotic Conditions,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 30:17, 3127-3131, DOI: 10.1080/00397910008086921
To link to this article: http://dx.doi.org/10.1080/00397910008086921
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