Journal of the Chemical Society, Dalton Transactions p. 403 - 406 (1980)
Update date:2022-08-10
Topics:
Booth, Brian L.
Casey, Geoffrey C.
Haszeldine, Robert N.
Octacarbonyldicobalt reacts with the dichlorocarbene precursor Hg(CCl3)Ph at 60 deg C in hexane to afford A similar complex is also obtained at 30 deg C, i.e. under conditions where appreciable thermal decomposition of Hg(CCl3)Ph to HgPhCl and CCl2 does not occur.Trapping expriments using cyclohexane have demonstrated that under both sets of conditions dichlorocarbene is formed.Possible mechanisms to explain the formation of the carbene and
Zhejiang Chemline International Co., Ltd.
Contact:+86-571-88062298
Address:Hengdian Industry Area, Dongyang, Zhejiang, China
Buffett (China) Holding Co.,Ltd
Contact:4006570891
Address:
website:http://www.antaibio.com
Contact:0086-21-65663057
Address:Room 2108, Building 2，No. 489 Zhengli Road，200433
website:http://www.chemdow.com
Contact:0086-10-82435335
Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
website:http://www.weichichem.com
Contact:+8613912949432
Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Doi:10.1021/cg201351j
(2012)Doi:10.1016/j.molcatb.2013.08.018
(2013)Doi:10.1039/b211585a
(2003)Doi:10.1002/zaac.200700127
(2007)Doi:10.1021/acs.orglett.9b02169
(2019)Doi:10.1246/bcsj.29.88
(1956)
