Journal of the Chemical Society, Dalton Transactions p. 403 - 406 (1980)
Update date:2022-08-10
Topics:
Booth, Brian L.
Casey, Geoffrey C.
Haszeldine, Robert N.
Octacarbonyldicobalt reacts with the dichlorocarbene precursor Hg(CCl3)Ph at 60 deg C in hexane to afford A similar complex is also obtained at 30 deg C, i.e. under conditions where appreciable thermal decomposition of Hg(CCl3)Ph to HgPhCl and CCl2 does not occur.Trapping expriments using cyclohexane have demonstrated that under both sets of conditions dichlorocarbene is formed.Possible mechanisms to explain the formation of the carbene and
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