Tetrahedron Letters p. 3829 - 3832 (1998)
Update date:2022-08-17
Topics:
Khurana, Jitender M.
Ray, Abhijit
Singh, Sarika
The deoxygenations of a variety of acyclic sulfoxides and selenoxides have been reported with nickel boride in THF at 0-5°C in nearly quantitative yields. The deoxygenations are proposed to proceed by an oxidative-addition and reductive-elimination mechanism.
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