NO reduction with ethanol on Pd-Mo/Al2O3 catalysts

Article abstract of DOI:10.1016/S0021-9517(03)00272-0

The NO reduction with ethanol was studied on Pd/Al₂O ₃ and Pd-Mo/Al₂O₃ catalysts. The Pd/Al ₂O₃ catalyst was more active for NO conversion, although the selectivity for N₂ formation was the same on both catalysts. IR and TPD analysis of adsorbed ethanol showed formation of stable acetate species upon dehydrogenation of ethanol to acetaldehyde at reaction temperature. TPSR measurements suggested that NO preferentially adsorbs on Pd while ethanol selectively adsorbs on alumina and/or partially reduced molybdenum oxide (MoO_x). The catalytic results further suggested that the reaction mechanism was the same on both catalysts and that the reaction occurred between adsorbed NO and acetate species at the metal/oxide interface. A reaction mechanism was proposed where the limiting step was the dehydrogenation of ethanol to acetaldehyde.