Palladium-Catalyzed Intramolecular Addition of Amines to Acetylenes. Synthesis of Cyclic Imines

DOI: 10.1021/jo00020a023

Source and publish data:

Journal of Organic Chemistry p. 5812 - 5816 (1991)

Update date:2022-08-17

Topics:

Authors:

Fukuda, Yukitoshi

Matsubara, Seijiro

Utimoto, Kiitiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00020a023

Intramolecular aminopalladation of alkynylamines gave intermediary alkenylpalladium compounds that hydrolyzed and isomerized to thermodynamically stable cyclic imines.Treatment of 3-alkynylamines with a catalytic amount of PdCl2(MeCN)2 gave exclusively 1-

Full text of DOI:10.1021/jo00020a023

Products guided by the article

Product name:3-Octyn-1-ol, 4-methylbenzenesulfonate

Cas No:100419-71-4

R&D Labs maybe for 100419-71-4

HuiFeiChem PharmaTech Co.Ltd

Contact:0510-85393305

Address:1619 Huishan Avenue, Huishan District, Wuxi,
HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China
Jai Radhe Sales

website:http://www.jairadhesales.com

Contact:0091-79-26431096

Address:309 Harikrupa Tower,Nr old Sharda Mandir Char Rasta,Ellisbridge
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China

Relevant to this article

Doi:10.1021/ja00480a070
(1978)
Coordination among Bond Formation/Cleavage in a Bifunctional-Catalyzed Fast Amide Hydrolysis: Evidence for an Optimized Intramolecular N-Protonation Event

Doi:10.1021/acs.joc.9b03383
(2020)
Remarkably stable (Me₃Al)₂·DABCO and stereoselective nickel-catalyzed AlR₃ (R = Me, Et) additions to aldehydes

Doi:10.1002/anie.200462569
(2005)
Cu(ii) anchored nitrogen-rich covalent imine network (Cu^II-CIN-1): An efficient and recyclable heterogeneous catalyst for the synthesis of organoselenides from aryl boronic acids in a green solvent

Doi:10.1039/c4ra08909j
(2014)
Doi:10.1021/ja00709a024
(1970)
Friedel-Crafts alkylation of toluene with tert-butyl alcohol over Fe₂O₃-modified Hβ

Doi:10.1039/c6ra21054f
(2016)

Article Doi