THE HYDRIDOPENTACYANOCOBALTATE ANION INDUCED DEOXYGENATION OF ALLYLIC ALCOHOLS USING β-CYCLODEXTRIN AS A PHASE TRANSFER AGENT

DOI: 10.1016/S0040-4039(00)97553-1

Source and publish data:

Tetrahedron Letters p. 4101 - 4104 (1990)

Update date:2022-08-28

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Authors:

Lee, Jong-Tae

Alper, Howard

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Article abstract of DOI:10.1016/S0040-4039(00)97553-1

β-Cyclodextrin promotes the deoxygenation of allylic alcohols to olefins using hydrogen and the in situ generated hydridopentacyanocobaltate anion.Internal olefins, of trans-stereochemistry, are the principal reaction products (i. e., no cis-products are formed).

Full text of DOI:10.1016/S0040-4039(00)97553-1

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