Electrochemical synthesis of ketones from acid chlorides and alkyl and aryl halides catalysed by nickel complexes

DOI: 10.1016/0022-328X(89)85195-2

Source and publish data:

Journal of Organometallic Chemistry p. C47 - C50 (1989)

Update date:2022-08-11

Topics:

Authors:

Marzouk, H.

Rollin, Y.

Folest, J. C.

Nedelec, J. Y.

Perichon, J.

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Article abstract of DOI:10.1016/0022-328X(89)85195-2

The nickel-catalysed electrochemical cross-coupling of acid chlorides and alkyl or aryl halides in acetonitrile affords unsymmetric ketones in good to high yields.The reaction can be performed under very simple and mild conditions in a diaphragmless cell.A zinc rod as the sacrificial anode has been found to be the most efficient.

Full text of DOI:10.1016/0022-328X(89)85195-2

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