Tetrahedron Letters p. 1915 - 1918 (1997)
Update date:2022-08-30
Topics:
Legros, Jean-Yves
Toffano, Martial
Drayton, Sally K.
Rivard, Michael
Fiaud, Jean-Claude
Secondary benzylic alcohols were kinetically resolved by rabbit gastric lipase-mediated acylation with isopropenyl acetate. Among all the substrates tested, a high enantioselectivity was observed only for 1-[2-(6-methoxy)naphthyl]ethanol 3a (E>500). Allylic alcohols 14a and 15a were also efficiently resolved (E = 26 and 51 respectively).
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