Tetrahedron Letters p. 5371 - 5376 (2015)
Update date:2022-08-17
Topics:
Zhang, Hui
Wang, Chunjie
Li, Zhiwei
Wang, Ziyun
A Pd-catalyzed denitrogenative Hiyama coupling of arylhydrazines and aryl silanes is described under mild conditions. The newly developed catalytic system does not require the use of expensive silver- or copper-based stoichiometric oxidants to obtain diaryl derivatives with high selectivity and reactivity. The reported coupling reactions are very practical as they do not require the protection of inert gas or oxygen and are tolerant to many functional groups.
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