Bifunctional Catalysts for Regioselective Hydrogenation and for Hydrogenation of Highly-substituted Alkenes

DOI: 10.1039/c39860000977

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Journal of the Chemical Society. Chemical communications p. 977 - 978 (1986)

Update date:2022-08-12

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Authors:

Preston, Sheila A.

Cupertino, Domenico C.

Palma-Ramirez, Pilar

Cole-Hamilton, David J.

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Article abstract of DOI:10.1039/c39860000977

catalyses the hydrogenation of highly-substituted acrylic acids in the presence of base by a mechanism involving chelate stabilisation of alkene co-ordination and base-catalysed transesteification of the co-ordinated mixed anhydride; for hexa-2,4-dienoic acid, selective hydrogenation of the αβ double bond occurs.

Full text of DOI:10.1039/c39860000977

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