The influence of electronic effects and temperature on the enantioselective reductions of acetophenone derivatives with (-)-diisopinocampheylchloroborane - A dynamic model of enantioselection

Article abstract of DOI:10.1016/0957-4166(96)00285-6

The asymmetric reduction of acetophenone derivatives with (-)-diisopinocampheylchloroborane, with respect to temperature and different electronic situations present in the carbonyl group, has been investigated. The temperature dependence of enantioselecti