Chemistry Letters p. 1453 - 1456 (1985)
Update date:2022-08-17
Topics:
Fujisawa, Tamotsu
Umezu, Kazuto
Sato, Toshio
1-Chloro-2-methyl-N,N-tetramethylenepropenylamine was found to be a good condensation reagent for the regioselective coupling reaction of allylic alcohols with lithium enolate of dithioesters under mild conditions to afford γ,δ-unsaturated dithioesters, which proceeds by a thio-Claisen rearrangement of S-allylic ketene dithioacetals initially formed.
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