CHIMIE ORGANOMETALLIQUE SOUS HAUTE PRESSION: REACTION DES CHLOROCETONES AVEC L'HYDRURE DE TRIBUTYLETAIN

Article abstract of DOI:10.1016/0022-328X(85)80067-X

High-pressure reaction of tributyltin hydride with several chloroketones (3-chloro-2-butanone, 4-chloro-2-butanone, 5-chloro-2-pentanone, 6-chloro-2-hexanone and 7-chloro-2-heptanone) led to the formation of chloroalkoxytins or cyclic ethers.An ionic mechanism, starting with nucleophilic attack at the carbonyl group, is proposed to explain the formation of the reaction products.