Reaktionen von Triorganylstannyldiazoessigsaeureestern mit Brompentacarbonylmangan

DOI: 10.1016/0022-328X(91)86149-K

Source and publish data:

Journal of Organometallic Chemistry p. 233 - 241 (1991)

Update date:2022-08-11

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Authors:

Kandler, Helmut

Bosch, Henry William

Shklover, Valery

Berke, Heinz

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Article abstract of DOI:10.1016/0022-328X(91)86149-K

Manganese pentacarbonyl bromide reacts with 2 equivalents of alkyl triorganylstannyldiazoacetates 1a-d to form the tetracarbonyl-μ(C,O)(1,2-alkoxycarbonyl-2-triorganylstannylethen-1-yl)manganese compounds 2a-d, presumably via the carbyne intermediate 3.Co

Full text of DOI:10.1016/0022-328X(91)86149-K

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