A versatile modular approach to new chiral C2-symmetrical ferrocenyl ligands: Highly enantioselective Rh-catalyzed hydrogenation of α- acetamidoacrylic acid derivatives

DOI: 10.1016/S0040-4039(98)01832-2

Source and publish data:

Tetrahedron Letters p. 8073 - 8076 (1998)

Update date:2022-08-11

Topics:

Authors:

Almena Perea, Juan J.

Boerner, Armin

Knochel, Paul

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Article abstract of DOI:10.1016/S0040-4039(98)01832-2

An easy, efficient, flexible modular synthesis of a new family of chiral C₂-symmetrical ferrocenyl diphosphines (FERRIPHOS) is described. These new ligands gave high enantioselectivities (up to 99.4% ee) in the rhodium- catalyzed hydrogenation of different enamide derivatives.

Full text of DOI:10.1016/S0040-4039(98)01832-2

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