Tetrahedron Letters p. 4077 - 4080 (1991)
Update date:2022-08-17
Topics:
Rabasco, John J.
Kass, Steven R.
Gas-phase elimination reactions of deuterium labeled 3-methoxycyclohexenes have been investigated. 1,4-Elimination is heavily favored over 1,2-elimination when strong bases such as hydroxide and amide are used. The 1,2-pathway becomes more competitive when weaker bases such as methoxide are employed, and the mechanism shifts from E1 cB to E2.
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