OXIDATION VON DICHLORMETHAN ZU EINEM CARBONAT-LIGANDEN

DOI: 10.1016/S0022-328X(00)98838-7

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1983)

Update date:2022-08-10

Topics:

Authors:

Scherer, O. J.

Jungmann, H.

Huessong, K.

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Article abstract of DOI:10.1016/S0022-328X(00)98838-7

The reaction of CH2Cl2 with (Ph3P)2PtO2 affords cis-(Ph3P)2PtCl2, (Ph3P)2Pt(CO3), Ph3PO and H2O. 31P<1H> NMR studies of this oxidation of CH2Cl2 to a carbonato ligand give evidence for the intermediates (Ph3P)2Pt(OOCH2Cl)Cl and .With formic acid (Ph3P)2PtO2 yields the formate complex cis<(Ph3P)2Pt(OOCH)2>.

Full text of DOI:10.1016/S0022-328X(00)98838-7

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