CONCERNING THE MECHANISM OF A CYANOMETALLATE MEDIATED CARBONYLATION REACTION

DOI: 10.1016/S0040-4039(00)88679-7

Source and publish data:

Tetrahedron Letters p. 3999 - 4002 (1982)

Update date:2022-08-24

Topics:

Authors:

Rosario, R. del

Stuhl, L. S.

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Article abstract of DOI:10.1016/S0040-4039(00)88679-7

The ^2- anion (I) reacts with either one or two equivalents of benzyl bromide in either water/acetone or anhydrous acetonitrile to produce mainly 1,3-diphenyl-2-propanone.Excess carbon monoxide inhibitis the reaction.These results are interpreted as indicating that I is an intermediate in the reaction of K4 with CO and PhCH2Br to form 1,3-diphenyl-2-propanone.

Full text of DOI:10.1016/S0040-4039(00)88679-7

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