CONCERNING THE MECHANISM OF A CYANOMETALLATE MEDIATED CARBONYLATION REACTION

DOI: 10.1016/S0040-4039(00)88679-7

Source and publish data:

Tetrahedron Letters p. 3999 - 4002 (1982)

Update date:2022-08-24

Topics:

Authors:

Rosario, R. del

Stuhl, L. S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88679-7

The ^2- anion (I) reacts with either one or two equivalents of benzyl bromide in either water/acetone or anhydrous acetonitrile to produce mainly 1,3-diphenyl-2-propanone.Excess carbon monoxide inhibitis the reaction.These results are interpreted as indicating that I is an intermediate in the reaction of K4 with CO and PhCH2Br to form 1,3-diphenyl-2-propanone.

Full text of DOI:10.1016/S0040-4039(00)88679-7

Products guided by the article

Product name:1,3-Diphenylacetone

Cas No:102-04-5

R&D Labs maybe for 102-04-5

Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
Chongqing Changfeng Chemical Co., Ltd.

website:http://www.changfengchem.com

Contact:+86-23-67896333

Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city

Relevant to this article

Phenyl-1,3,5-trithienyl-diketopyrrolopyrrole: A molecular backbone potentially affording high efficiency for solution-processed small-molecule organic solar cells through judicious molecular design

Doi:10.1002/asia.201300371
(2013)
Development of catalysts for the Baylis-Hillman reaction: The application of tetramethylguanidine and attempts to use a supported analogue

Doi:10.1039/b106267k
(2001)
Mechanism of Chlorine Dioxide and Chlorate Ion Formation from the Reaction of Hypobromous Acid and Chlorite Ion

Doi:10.1021/ic980262q
(1998)
Synthesis of nitriles from aldoximes using silica gel as catalyst under microwave irradiation

Doi:10.1081/SCC-120022486
(2003)
Synthesis of Functionalized Carbon-Sulfur [5]Helicene: Pd-Catalyzed Negishi Cross-Coupling between the β-Positions of Thiophenes

Doi:10.1055/s-2003-43335
(2004)
Defect-mediated selective hydrogenation of nitroarenes on nanostructured WS₂

Doi:10.1039/c9sc03337h
(2019)

Article Doi