Journal of Organometallic Chemistry p. 143 - 146 (1981)
Update date:2022-08-17
Topics:
Berryhill, Stuart R.
Sharenow, Brett
Reaction of η5-C5H5Fe(CO)2SiMe3 with either n-BuLi or lithium diisopropylamide (LDA) results in a migration of the trimethylsilyl group from iron to the complexed Cp ligand.The resulting η5-C5H4SiMe3Fe(CO)2 anion is redily alkylated to give ?-bonded derivatives.The unique reactivity of the trimethylsilyl system is underscored by comparison with the behavior of η5-C5H4Fe(CO)2Me under identical conditions.Some chemical transformations of η5-C5H4SiMe3Fe(CO)2R derivatives involving migratory insertion and β-hydride abstraction are also reported.
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