Journal of Organometallic Chemistry p. 5 - 18 (1986)
Update date:2022-08-18
Topics:
Hill, E. Alexander
Harder, Constance L.
Wagner, Richard
Meh, David
Bowman, Richard P.
Reaction of cis- or trans-2-phenylcyclobutylmethyl bromide with magnesium produces the rearranged 5-phenyl-1-penten-5-ylmagnesium compound 7 in addition to the unrearranged Grignard reagent 6.The former appears to result from very rapid rearrangement of a radical intermediate in the process of Grignard reagent formation.Rearrangement of 6 to 7 also occurs, at a rate which is accelerated by the phenyl group.
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(1931)
