Advanced Synthesis and Catalysis p. 201 - 206 (2016)
Update date:2022-08-11
Topics:
Huang, Jiapian
Yang, Yi
Chen, Zhiyuan
A synthetically useful 1,3-insertion reaction of a rhodium-carbenoid into the C(sp2)?H bond of simple indole is disclosed, which produces structurally divergent 2-indolylenamides in good to excellent yields and decent chemo- and regioselectivities. The obtained tryptamine vinylogues can be transformed into biologically important tryptamine derivatives or 3,3′-biindoles with ease.
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