Tetrahedron Letters (2020)
Update date:2022-08-11
Topics:
Angelini, Tommaso
Roseblade, Stephen
Zanotti-Gerosa, Antonio
The efficient, solvent-free homogeneous hydrogenation of aldehydes has been accomplished using the catalysts [RuCl2(dppb)(ampy)] and [RuCl2(dppf)(ampy)], providing high conversion to the corresponding alcohols at molar catalyst loadings of 10,000/1–50,000/1. A solvent-free protocol has been developed, allowing aldehydes to be efficiently reduced avoiding by-product formation and with minimal waste generation.[Formula presented]
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Doi:10.1016/S0022-328X(00)84449-6
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