High-valent Oxo Complexes of Osmium as Selective Oxidants for Cyclohexene Oxidation. Complexation of the Bisamide Tetradentate Ligand bpb to Osmium and the X-Ray Structure of trans-<bpbH2 = N,N'-Bis(2'-pyridinecarboxamide)-1,2-benzen

DOI: 10.1039/c39860000200

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Journal of the Chemical Society. Chemical communications p. 200 - 202 (1986)

Update date:2022-08-24

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Authors:

Che, Chi-Ming

Cheng, Wing-King

Mak, Thomas C. W.

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Article abstract of DOI:10.1039/c39860000200

The reaction of N,N'-bis(2'-pyridinecarboxamide)-1,2-benzene (bpbH2) with K2 yielded trans-(2+) which in turn gave trans- upon treatment with PPh3; the Os(III) complex has been characterized by X-ray cryst

Full text of DOI:10.1039/c39860000200

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