Tetrahedron Letters p. 707 - 710 (1989)
Update date:2022-08-15
Topics:
Lomas, John S.
Briand, Sylvette
In the thermolysis of tri-(1-adamantyl)methanol about 55percent of the di-(1-adamantyl)-ketyl amd 1-adamantyl radicals escape from the solvent cage, the former transferring hydrogen to benzophenone and the second abstracting hydrogen from the solvent, toluene, with isotope effects on the latter reaction consistent with tunnelling.
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