Chemistry Letters p. 769 - 770 (1998)
Update date:2022-08-29
Topics:
Fujiwara, Hiroaki
Yamashita, Mayumi
Murakoshi, Kei
Wada, Yuji
Yanagida, Shozo
CdS nanocrystallites catalyzed photoallylation of benzyl halide (BZX, X=Br or Cl) with allyltributyltin in N, N-dimethylformamide (DMF) under visible-light irradiation, giving 4-phenyl-1-butene. The reaction proceeds via bimolecular coupling between benzyl radical and allyl radical, which are formed by photo-excited electrons and holes pairs on the surface of quantized CdS nanocrystallites.
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