Journal of the American Chemical Society p. 6252 - 6254 (1988)
Update date:2022-08-11
Topics:
Kropp, Michael
Bhamidapaty, Kaumudi
Schuster, Gary B.
We report the preparation, structure, and characterization of the first example of a new class of boron-containing compounds.Irradiation of tetramethylammonium triphenylstyrylborate (1) in an acetonitrile solution at 254 nm converts it to trans-1,1,2,3-tetraphenylboratirane (2), eq. 1.Boratirane 2 is a stable, air and water sensitive, colorless crystalline solid.
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