Journal of the Chemical Society. Chemical communications p. 693 - 695 (1986)
Update date:2022-08-11
Topics:
Tomioka, Hideo
Sugiura, Tsugunori
Masumoto, Yoshinao
Izawa, Yasuji
Inagaki, Satoshi
Iwase, Koji
Experimental and theoretical analyses of 1,2-H shifts in singlet carbene RCH2-C(:)-X (X = Cl, Ph) indicate that hyperconjugation of the carbene lone pair and the low-lying C-R ?* orbital of the β-substituent plays an important role in determining the relative population of the carbene conformers.
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