Experimental and Theoretical Analysis of the Factors determining the Conformation and Stability of Singlet Carbene

DOI: 10.1039/c39860000693

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 693 - 695 (1986)

Update date:2022-08-11

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Authors:

Tomioka, Hideo

Sugiura, Tsugunori

Masumoto, Yoshinao

Izawa, Yasuji

Inagaki, Satoshi

Iwase, Koji

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Article abstract of DOI:10.1039/c39860000693

Experimental and theoretical analyses of 1,2-H shifts in singlet carbene RCH2-C(:)-X (X = Cl, Ph) indicate that hyperconjugation of the carbene lone pair and the low-lying C-R ?^* orbital of the β-substituent plays an important role in determining the relative population of the carbene conformers.

Full text of DOI:10.1039/c39860000693

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