Journal of Organometallic Chemistry p. 257 - 268 (1983)
Update date:2022-08-17
Topics:
Bickley, Douglas G.
Hao, Nguyen
Bougeard, Peter
Sayer, Brian G.
Burns, Robert C.
McGlinchey, Michael J.
The polymeric (Cp2ZrH2)x molecule is shown by 1H NMR studies to adopt a dimeric structure with bridging and terminal hydride ligands in both benzene-d6 and toluene-d8 solution.The reaction of the zirconium dihydride with diphenylacetylene has been re-investigated and produces a zirconacyclopentadiene complex 7, contrary to literature suggestions of a dimetallic zirconabenzene structure.A qualitative molecular orbital analysis of the a suggested mechanism involving reaction with diphenylacetylene via a dimeric species.
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