Journal of Organic Chemistry p. 4848 - 4853 (1989)
Update date:2022-08-11
Topics:
Becker, Sandrine
Fort, Yves
Vanderesse, Regis
Caubere. Paul
It is shown that nickel-containing complex reducing agents alone or in the presence of 2,2'-bipyridine (NiCRA and NiCRAL-bpy, respectively) are very efficient in the desulfurization of sulfur containing organic compounds.A number of functional groups are resistant.Advantages of the inexpensive and nonpyrophoric CRA's are their easy preparation and handling.The mechanism of these desulfuryzations are discussed and compared to those with Ni(0) complexes.
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