Tetrahedron Letters p. 3617 - 3620 (1981)
Update date:2022-08-17
Topics:
Sekine, Mitsuo
Kume, Akiko
Hata, Tsujiaki
Diethyl benzoylphosphonate (1) underwent facile benzoylation of alcohols in the presence of DBU.Reactions of diols containing primary and secondary hydroxyl groups with 1 gave predominantly monobenzoates in which primary hydroxyl groups were highly selectively benzoylated.Related acylations were also described.
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