DIALKYL ACYLPHOSPHONATES: A NEW ACYLATING AGENT OF ALCOHOLS

DOI: 10.1016/S0040-4039(01)81975-4

Source and publish data:

Tetrahedron Letters p. 3617 - 3620 (1981)

Update date:2022-08-17

Topics:

Authors:

Sekine, Mitsuo

Kume, Akiko

Hata, Tsujiaki

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Article abstract of DOI:10.1016/S0040-4039(01)81975-4

Diethyl benzoylphosphonate (1) underwent facile benzoylation of alcohols in the presence of DBU.Reactions of diols containing primary and secondary hydroxyl groups with 1 gave predominantly monobenzoates in which primary hydroxyl groups were highly selectively benzoylated.Related acylations were also described.

Full text of DOI:10.1016/S0040-4039(01)81975-4

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