Potassium fluoride on alumina: Synthesis of O-aryl N,N-dimethylthiocarbamates and their rearrangement into S-aryl N,N-dimethylthiocarbamates under microwave irradiation

Article abstract of DOI:10.1080/00397919608004558

A series of O-aryl N,N-dimethyl thiocarbamates have been prepared by the reaction of dimethylthiocarbamoyl chloride with phenols absorbed on potassium fluoride on alumina. The rearrangement of O-aryl N,N-dimethylthiocarbamate into S-aryl N,N-dimethylthiocarbamate under microwave irradiation was also studied. The use of conductive support like graphite or silicon carbide allow these rearrangements although the O-aryl N,N-dimethylthiocarbamates have very low dielectric lost.

Full text of DOI:10.1080/00397919608004558

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Potassium Fluoride on Alumina:
Synthesis of O-Aryl N,N-
Dimethylthiocarbamates
and their Rearrangement
into S-Aryl N,N-Dimethyl-
Thiocarbamates Under
Microwave Irradiation
a
a
Didier Villemin , Messaoud Hachemi & Mekki
a
Lalaoui
a
Ecole Nationale Supěrieure d' Ingénieurs de Caen,
I.S.M.R.A., Groupe Catalyse et Modélisation ,
(U.R.A. 480) F-14050, Caen Cedex, France
Published online: 23 Aug 2006.
To cite this article: Didier Villemin , Messaoud Hachemi & Mekki Lalaoui (1996)
Potassium Fluoride on Alumina: Synthesis of O-Aryl N,N-Dimethylthiocarbamates
and their Rearrangement into S-Aryl N,N-Dimethyl-Thiocarbamates Under
Microwave Irradiation, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 26:13, 2461-2471, DOI:
10.1080/00397919608004558
To link to this article: http://dx.doi.org/10.1080/00397919608004558
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