A New Oxidative Cleavage of 2-Nitrocycloalkanones by Hydrogen Peroxide: An Important, Efficient Method for Dicarboxylic Acid or Ketoacid Synthesis

DOI: 10.1055/s-1988-27754

Source and publish data:

Synthesis p. 915 - 917 (1988)

Update date:2022-08-11

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Authors:

Ballini, Roberto

Marcantoni, Enrico

Petrini, Marino

Rosini, Goffredo

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Article abstract of DOI:10.1055/s-1988-27754

2-Nitrocycloalkanones are smoothly converted into dicarboxylic acids or ketoacids, depending on whether the nitro group is secondary or tertiary, by treatment with aqueous 30percent hydrogen peroxide and potassium carbonate in methyl alcohol solution for 8-10 h at room temperature.

Full text of DOI:10.1055/s-1988-27754

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