Nucleophilic trifluoromethylation of organic substrates using (trifluoromethyl)trimethylsilane in the presence of a fluoride anion. II. A convenient route to aryltrifluoromethyl-sulfides, - sulfoxides and -sulfones

DOI: 10.1016/0022-1139(94)03124-I

Source and publish data:

Journal of Fluorine Chemistry p. 255 - 258 (1995)

Update date:2022-08-11

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Authors:

Movchun, Valeria N.

Kolomeitsev, Alexander A.

Yagupolskii, Yurii L.

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Article abstract of DOI:10.1016/0022-1139(94)03124-I

Aryltrifluoromethyl-sulfides, -sulfoxides and -sulfones can be prepared by trifluoromethylation of the corresponding arylsulfenyl, -sulfinyl and -sulfonyl halides using (trifluoromethyl)trimethylsilane in the presence of fluoride sources, such as TASF . - Keywords: Nucleophilic trifluoromethylation; (Trifluoromethyl)trimethylsilane; Fluoride anion; Aryltrifluoromethylsulfides; Aryltrifluoromethylsulfoxides; Aryltrifluoromethylsulfones

Full text of DOI:10.1016/0022-1139(94)03124-I

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