Tetrahedron Letters p. 5149 - 5150 (1996)
Update date:2022-08-11
Topics:
Iseki, Katsuhiko
Kuroki, Yoshichika
Takahashi, Mie
Kobayashi, Yoshiro
The asymmetric allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes catalyzed by substoichiometric quantities of chiral phosphoramides were carried out with good enantiomeric excess (up to 88% ee). Phosphoramides 3 and 4, prepare
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