Journal of the Chemical Society. Chemical communications p. 1533 - 1534 (1995)
Update date:2022-08-04
Topics:
Kitayama, Kenji
Uozumi, Yasuhiro
Hayashi, Tamio
Asymmetric hydrosilylation of styrenes (ArCH=CHR) with trichlorosilane in the presence of a palladium catalyst (0.1 molpercent) bearing a new chiral monodentate phosphine ligand, (S)-2-diphenylphosphino-1,1'-binaphthyl <(S)-H-MOP>, followed by oxidation of the resulting 1-aryl-1-silylalkanes, gives optically active benzylic alcohols of up to 96percent enantiomeric excess (e.e.).
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