Synthesis p. 631 - 633 (1987)
Update date:2022-08-16
Topics:
Sera, Akira
Tani, Hiroyuki
Nishiguchi, Ikuzo
Hirashima, Tsuneaki
Electroreduction of 1-nitro-1-alkenes in the presence of titanium(IV) chloride affords nitriles in good yields.This procedure provides a facile transformation of aldehydes to one-carbon elongated nitriles since the 1-nitro-1-alkenes are best prepared from aldehydes and nitromethane.
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