PALLADIUM-CATALYZED CONJUGATE REDUCTION OF α,β-UNSATURATED CARBONYL COMPOUND WITH TRIBUTYLTIN HYDRIDE. THE PROMOTING INFLUENCE OF THE PRESENCE OF PROTONIC OR LEWIS ACIDS.

DOI: 10.1016/S0040-4039(00)86751-9

Source and publish data:

Tetrahedron Letters p. 1825 - 1828 (1982)

Update date:2022-08-10

Topics:

Authors:

Four, P.

Guibe, F.

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Article abstract of DOI:10.1016/S0040-4039(00)86751-9

Acetic acid or ZnCl2 promote the palladium-catalyzed selective conjugate reduction of α,β-unsaturated carbonyl compounds with tributyltin hydride.Protonic agents also promote the palladium-catalyzed hydrogenolysis of aryl allyl ethers and allyl carbamates.

Full text of DOI:10.1016/S0040-4039(00)86751-9

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