Tetrahedron Letters p. 9041 - 9044 (1999)
Update date:2022-08-28
Topics:
Kondo, Yuichiro
Kon-i, Kana
Ooi, Takashi
Maruoka, Keiji
A conceptually new amphiphilic cleavage of the αβ C-C bonds of γ-iodo carbonyl substrates has been realized by the effective use of a combined Lewis acid/base system consisting of aluminum tris(2,6-diphenylphenoxide) (ATPH)/t-BuLi. This new amphiphilic bond cleavage reaction can be applied to a wide variety of γ-iodo carbonyl substrates and therefore serves as a highly efficient and general route to both cyclic and acyclic unsaturated carbonyl compounds.
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