Journal of the American Chemical Society
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Experimental details, Table S1 and Figures S1 – S22. This material
is available free of charge via the Internet at http://pubs.acs.org.
(6) Hu, K.; Sampaio, R. N.; Marquard, S. L.; Brennaman, M. K.; Tamaki, Y.;
Meyer, T. J.; Meyer, G. J. A High-Valent Metal-Oxo Species Produced by
Photoinduced One-Electron, Two-Proton Transfer Reactivity. Inorg.
Chem. 2018, 57, 486-494.
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AUTHOR INFORMATION
(7) Han, J. W.; Jung, J.; Lee, Y.-M.; Nam, W.; Fukuzumi, S. Photocatalytic Ox-
idation of Benzene to Phenol Using Dioxygen as an Oxygen Source and
Water as an Electron Source in the Presence of a Cobalt Catalyst. Chem.
Sci. 2017, 8, 7119-7125.
Corresponding Author
(8) (a) Shen, D.; Saracini, C.; Lee, Y.-M.; Sun, W.; Fukuzumi, S.; Nam, W. Pho-
tocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an
Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Man-
ganese Complex. J. Am. Chem. Soc. 2016, 138, 15857-15860. (b) Fuku-
zumi, S.; Kishi, T.; Kotani, H.; Lee, Y.-M.; Nam, W. Highly Efficient Photo-
catalytic Oxygenation Reactions Using Water as an Oxygen Source. Nat.
Chem. 2011, 3, 38-41.
(9) (a) Chen, G.; Chen, L.; Ma, L.; Kwong, H.-K.; Lau, T.-C. Photocatalytic
Oxidation of Alkenes and Alcohols in Water by a Manganese(V) Nitrido
Complex. Chem. Commun. 2016, 52, 9271-9274. (b) Bai, L.; Li, F.; Wang,
Y.; Li, H.; Jiang, X.; Sun, L. Visible-Light-Driven Selective Oxidation of
Benzyl Alcohol and Thioanisole by Molecular Ruthenium Catalyst Modi-
fied Hematite. Chem. Commun. 2016, 52, 9711-9714. (c) Wu, X.; Yang,
X.; Lee, Y.-M.; Nam, W.; Sun, L. A Nonheme Manganese(IV)-Oxo Species
Generated in Photocatalytic Reaction Using Water as an Oxygen Source.
Chem. Commun. 2015, 51, 4013-4016. (d) Li, T.-T.; Li, F.-M.; Zhao, W.-
L.; Tian, Y.-H.; Chen, Y.; Cai, R.; Fu, W.-F. Highly Efficient and Selective
Photocatalytic Oxidation of Sulfide by a Chromophore-Catalyst Dyad of
Ruthenium-Based Complexes. Inorg. Chem. 2015, 54, 183-191.
Author Contributions
#
Y.H.H. and J.H. contributed equally to this work.
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Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENT
This work was supported by the NRF of Korea through CRI (NRF-
2012R1A3A2048842 to W.N) and Basic Science Research Program
(2017R1D1A1B03029982 to Y.M.L. and 2017R1D1A1B03032615
to S.F.) and the Grants-in-Aid (no. 16H02268 to S.F.) from MEXT.
We appreciate Dr. Muniyandi Sankaralingam for helping EPR meas-
urements.
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