Journal of the Chemical Society. Chemical communications p. 101 - 102 (1991)
Update date:2022-08-11
Topics:
Tanaka, Kazuhiko
Suzuki, Hitomi
Synthesis of (R)-(-)- and (S)-(+)-muscone of essentially 100percent enantiomeric excess (e.e.) by the conjugate addition of chiral methylcuprate to (E)-cyclopentadec-2-enone was accomplished by adding small amounts of tetrahydrofuran (THF) as an external ligand to a toluene solution of the chiral methylcuprate.
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