Clay catalysis: Storks alkylation and acylation of cyclohexanone without isolation of enamine

Article abstract of DOI:10.1080/00397919608005225

Cyclohexanone and morpholine in the presence of KSF under azeotropic distillation gave 1-morpholinocyclohexane which is alkylated or acylated in situ without isolation of the enamine. The overall yield of these Stork's reactions are better or equivalent to those obtained by isolation of the enamine.

Full text of DOI:10.1080/00397919608005225

This article was downloaded by: [UQ Library]
On: 09 September 2013, At: 21:23
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Clay Catalysis: Stork's
Alkylation and Acylation
of Cyclohexanone Without
Isolation of Enamine
Mohamed Hammadi a & Didier Villemin a
a Ecole Nationale Supérieure d'Ingénieurs de Caen
I.S.M.R.A., Université de Caen, U.R.A. 480 CANRS,
Caen Cedex, F-14050, France
Published online: 21 Aug 2006.
To cite this article: Mohamed Hammadi & Didier Villemin (1996) Clay Catalysis:
Stork's Alkylation and Acylation of Cyclohexanone Without Isolation of Enamine,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 26:15, 2901-2904, DOI: 10.1080/00397919608005225
To link to this article: http://dx.doi.org/10.1080/00397919608005225
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with

primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions