Chemistry Letters p. 1017 - 1020 (1984)
Update date:2022-08-17
Topics:
Tsuji, Jiro
Shimizu, Isao
Minami, Ichiro
Various terminal allylic compounds such as allylic esters, phenyl esters, carbonates, chlorides, and vinyl epoxides react with ammonium or sodium formate to give 1-olefins with high regioselectivity by using palladium-tributylphosphine complex as a catalyst.The reaction offers a useful synthetic method for 1-olefins.
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