Stereoselective synthesis of nucleosides by metallocene-promoted activation of glycosyl fluorides

DOI: 10.1016/S0040-4039(00)91869-0

Source and publish data:

Tetrahedron Letters p. 1093 - 1096 (1992)

Update date:2022-08-24

Topics:

Authors:

Matheu Ma.

Echarri Echarri

Castillon

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Article abstract of DOI:10.1016/S0040-4039(00)91869-0

The Cp₂MCl₂-AgX (M=Hf, Zr; X = ClO₄, OTf) mixture is very effective for the promotion of the coupling of glycosyl fluorides and bis(trimethylsilyl)uracil. The stereoselectivity of the reaction depends on the solvent employ

Full text of DOI:10.1016/S0040-4039(00)91869-0

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