Microbiological transformations. 23. A surprising regioselectivity of microbiological Baeyer-Villiger oxidations of menthone and dihydrocarvone

DOI: 10.1016/S0957-4166(00)80281-5

Source and publish data:

Tetrahedron Asymmetry p. 379 - 382 (1992)

Update date:2022-08-10

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Authors:

Alphand Alphand

Furstoss

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Article abstract of DOI:10.1016/S0957-4166(00)80281-5

Regioisomeric lactones (ee>98%) were obtained by microbiological Baeyer-Villiger oxidation of enantiomers of menthone and dihydrocarvone. The regioselectivity of the biotransformation is shown to be dependant upon the considered enantiomer. An improvement of our empirical model of the active site is suggested.

Full text of DOI:10.1016/S0957-4166(00)80281-5

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