Water accelerated Sm/TMSCl reductive system: Debromination of vic- dibromides and reduction of sodium alkyl thiosulfates

Article abstract of DOI:10.1080/00397910008087241

A simple and efficient method for the debromination of vic-dibromides to (E)-alkenes and reduction of sodium alkyl thiosulfates to disulfides promoted by Sm/TMSCl/H₂O (trace) has been described.

Full text of DOI:10.1080/00397910008087241

Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic
Chemistry
ISSN: 0039-7911 (Print) 1532-2432 (Online) Journal homepage: http://www.tandfonline.com/loi/lsyc20
Water Accelerated Sm/TMSCl Reductive System:
Debromination of VIC—Dibromides and Reduction
of Sodium Alkyl Thiosulfates
Xiaoliang Xu , Ping Lu & Yongmin Zhang
To cite this article: Xiaoliang Xu , Ping Lu & Yongmin Zhang (2000) Water Accelerated Sm/
TMSCl Reductive System: Debromination of VIC—Dibromides and Reduction of Sodium Alkyl
Thiosulfates, Synthetic Communications, 30:11, 1917-1925, DOI: 10.1080/00397910008087241
To link to this article: http://dx.doi.org/10.1080/00397910008087241
Published online: 04 Dec 2007.
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Date: 07 June 2016, At: 23:22