New Acyclic Approach to 3-Amino-2,3,6-trideoxy-L-hexoses: a Stereocontrolled Synthesis of N-Benzoyl L-Daunosamine

DOI: 10.1039/c39860000393

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Journal of the Chemical Society. Chemical communications p. 393 - 394 (1986)

Update date:2022-08-17

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Authors:

Hirama, Masahiro

Nishizaki, Itaru

Shigemoto, Takeo

Ito, Sho

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Article abstract of DOI:10.1039/c39860000393

N-Benzoyl L-daunosamine was synthesized stereoselectively starting from O-t-butyldimethylsilyl L-lactaldehyde and methyl propiolate; the crucial step, intramolecular conjugate addition of a carbamoyl amino group of methyl threo-5-carbamoyloxy-4-triethylsi

Full text of DOI:10.1039/c39860000393

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Product name:Propanoic acid, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, ethyl ester

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