Synthetic Studies on Arene-Olefin Cycloadditions-VIII. Total Syntheses of (+/-)-Silphiperfol-6-ene, (+/-)-7αH-Silphiperfol-5-ene and (+/-)-7βH-Silphiperfol-5-ene

DOI: 10.1016/S0040-4039(00)98278-9

Source and publish data:

Tetrahedron Letters p. 5987 - 5990 (1985)

Update date:2022-08-15

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Authors:

Wender, Paul A.

Singh, Sunil K.

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Article abstract of DOI:10.1016/S0040-4039(00)98278-9

Total syntheses of (+/-)-silphiperfol-6-ene, (+/-)-7αH-silphiperfol-5-ene and (+/-)-7βH-silphiperfol-5-ene are described in which a new element of stereoinduction in arene-olefin meta cycloadditions was tested and a new method for cycloadduct transformation was developed.

Full text of DOI:10.1016/S0040-4039(00)98278-9

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