Journal of Organic Chemistry p. 3901 - 3904 (1987)
Update date:2022-08-16
Topics:
Weiberth, Franz J.
Hall, Stan S.
The nucleophilic addition of Grignard reagents to nitriles, especially when using sterically demanding components, is effectively catalyzed by copper(I) salts.Alkyl and aromatic nitriles and a selection of Grignard reagents were employed to prepare sterically hindered ketimines after addition, ketones after a tandem addition-hydrolysis procedure, and branched primary amines after a tandem addition-reduction sequence.
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