LiHMDS: Facile, highly efficient and metal-free transesterification under solvent-free condition

Article abstract of DOI:10.1016/j.catcom.2020.106194

Transesterification is one of the important organic reactions employed in numerous industrial as well as laboratory applications for the synthesis of various esters. Herein, we report a rapid, highly efficient, and transition metal-free transesterification reaction in the presence of LiHMDS under solvent-free conditions. The transesterification reaction was carried out with three different benzoate esters and a wide range of primary and secondary alcohols (from C3-C18) in good to excellent yields (45 examples). By considering the commercial role of esters, this method will be promising for the facile synthesis of esters in industry-relevant applications.

Full text of DOI:10.1016/j.catcom.2020.106194

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Annals of Physical and Rehabilitation Medicine 56S (2013) e277
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Presentation de la session / Session presentation
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Pediatrie (1) – Orthopedie : scoliose idiopathique et rachis,
polyhandicap (session SOFMER-SFERHE)
Pediatrics (1) – Orthopedics: Idiopathic scoliosis and spine, multiple disabilities
(SOFMER-SFERHE session)
1. Version franc¸aise
Pourquoi une scoliose idiopathique survient-elle ? Peut-on
2. English version
Why does idiopathic scoliosis occur? Can we predict its
evolution? Can posturography help us understand this disease?
How does corset wearing affect spinal flexibility and
paravertebral muscular atrophy? How is the rachis organised
in the sagittal plane in patients suffering from growth-related
spinal dystrophy? These and other questions will be approached
here to enlighten members about recent scientific progress. Two
recent studies devoted to rehabilitative care and medical
problems of the patient with multiple disabilities will be
presented.
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predire son evolutivite ? La posturographie peut-elle nous aider
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a ce niveau ? Quel role joue le port d’un corset sur la souplesse
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rachidienne et l’amyoptrophie paravertebrale ? Comment est
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organise le rachis dans le plan sagittal chez les patients atteints
de dystrophie rachidienne de croissance ?
Autant de questions qui seront abordees ici et nous
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eclaireront sur les progres des connaissances scientifiques
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dans ce domaine en 2013.
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problemes medicaux du sujet polyhandicape en SSR seront
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Deux etudes recentes sur la prise en charge reeducative et les
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egalement abordes.
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1877-0657/$ – see front matter # 2013 Publie par Elsevier Masson SAS.
http://dx.doi.org/10.1016/j.rehab.2013.07.518