Journal of the Chemical Society. Chemical communications p. 103 - 104 (1990)
Update date:2022-08-25
Topics:
Howell, Amy R.
Pattenden, Gerald
Regioselective (1,4-) hydrocobaltation of myrcene (1) leads to a 2:1 mixture of (E)- and (Z)-allylcobaloximes (2) which can be converted via the corresponding hydroxylamines (5) to geraniol (6a) and nerol (6b); by contrast, in the presence of molecular oxygen, (2) is converted into the peroxyallylcobalt complex (7), a precursor to linalool (8) and to linalool oxide (10).
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Doi:10.1063/1.472128
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